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郑洪河教授课题组在ACS Energy Letters上发表论文

来源:球探体育比分老版本 发布者:金霞发布时间:2017-06-06浏览次数:120

题目:Ultrahigh-Capacity Organic Anode with High- Rate Capability and Long Cycle Life for Lithium-Ion Batteries

者:Yan Wang,1Yonghong Deng,3 Qunting Qu,1Xueying Zheng,1Jingyu Zhang,1Gao Liu,*2 Vincent S. Battaglia,2and Honghe Zheng*,1

位:1College of Physics, Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215006, PR China

2Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, United States

3Department of Materials Sciences, South University of Science and Technologies of China, Shenzhen, 518000, China

要:Organic rechargeable batteries have attracted extensive attention as a potential alternative for the current lithium-ion batteries. However, most of the reports are limited to organic macromolecules or modified small organic molecules which exhibit low reversible capacity, poor rate capability, and very limited cycle life. Herein, a small organic compound, maleic acid, is adopted as the anode for lithium ion batteries without any modification. It exhibits an ultrahigh reversible capacity of ca. 1500 mAh g?1 at 46.2 mA g?1 current density. Even at a high current density of 46.2 A g?1, the electrode still delivers a capacity of 570.8 mAh g?1. When cycled at 2.31 A g?1, a capacity retention of 98.1% is obtained after 500 cycles. The excellent performance of the maleic acid organic anode is ascribed to its small volume effect and unique lithium-ion storage mechanisms. This new type of organic anode material may have a great opportunity for large-scale energy-storage systems with high-power properties.

影响因子:12.277

原文链接:https://pubs.acs.org/doi/10.1021/acsenergylett.7b00622